✦ LIBER ✦

The discovery of a 3p rydberg state in benzene by three-photon resonant multiphoton ionization spectroscopy

✍ Scribed by P.M. Johnson; G.M. Korenowski

Publisher: Elsevier Science
Year: 1983
Tongue: English
Weight: 307 KB
Volume: 97
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(83)87182-6

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✦ Synopsis

A new lEau 3~,,~ Rydberg state is found in the three-photon spectrum of benzene at 56080 cm-', near the previously knou n r Asu state. The vibronic structure of these states is found to be intertwined and an esS vibration previously assigned to the rAzu state is suggested to belong to 'Ezu. This vibration is of s!!ch a frequency in both states as to indicate a considerable amount of valence character due to mLxing with the nearby lElu valence state-

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