Investigation of kinetics of 4-methylpentene-1 polymerization using Ziegler–Natta-type catalysts
✍ Scribed by R. Balaji; H. Kothandaraman; D. Rajarathnam
- Publisher
- John Wiley and Sons
- Year
- 2003
- Tongue
- English
- Weight
- 204 KB
- Volume
- 88
- Category
- Article
- ISSN
- 0021-8995
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## Abstract Heterogeneous Ziegler–Natta systems—MgCl~2~ (ethoxide type)/TiCl~4~/di‐__n__‐butyl phthalate (DNBP)/triethylaluminum (TEA)/dimethoxymethylcyclohexylsilane (DMMCHS) and SiO~2~/MgCl~2~ (ethoxide type)/TiCl~4~/DNBP/TEA/DMMCHS—were studied for the polymerization of propylene. The slurry pol
The concentration of active centers of a high-activity magnesium chloridesupported Ziegler-Natta catalyst has been determined using three different methods. The initial active center concentration has been determined by quenching the reaction slurry with MeOT. To determine the concentration of the p