Study of the morphology and kinetics of novel Ziegler–Natta catalysts for propylene polymerization
✍ Scribed by Mohammed Abboud; Peter Denifl; Karl-Heinz Reichert
- Publisher
- John Wiley and Sons
- Year
- 2005
- Tongue
- English
- Weight
- 324 KB
- Volume
- 98
- Category
- Article
- ISSN
- 0021-8995
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📜 SIMILAR VOLUMES
The polymerization of propylene using a mixture of racemic metallocenes and Ziegler-Natta catalysts was investigated. The polypropylene was obtained as a mixture of a fine powder and beads, with the powder being absorbed partially on the beads. The relative amount of the powder can be controlled by
Grignard reagent PhMgCl was added during the preparation of the catalyst system MgCl 2 /di-n-butyl phthalate (DNBP)/TiCl 4 {AlEt 3 /diphenyl dimethoxyl silane (DPDMS) to improve its performance. It was found that PhMgCl could enhance both the activity of the catalyst and the isotacticity of the prod
## Abstract Heterogeneous Ziegler–Natta systems—MgCl~2~ (ethoxide type)/TiCl~4~/di‐__n__‐butyl phthalate (DNBP)/triethylaluminum (TEA)/dimethoxymethylcyclohexylsilane (DMMCHS) and SiO~2~/MgCl~2~ (ethoxide type)/TiCl~4~/DNBP/TEA/DMMCHS—were studied for the polymerization of propylene. The slurry pol