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Investigation of electrochemical electron transfer reactions with a scanning tunneling microscope: a theoretical study

โœ Scribed by Wolfgang Schmickler


Publisher
Elsevier Science
Year
1993
Weight
73 KB
Volume
295
Category
Article
ISSN
0167-2584

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โœ Wolfgang Schmickler ๐Ÿ“‚ Article ๐Ÿ“… 1995 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 352 KB

The redox density of states of a redox couple is discussed within the framework of quantum mechanical theories of electron transfer reactions. It may exhibit oscillations if the energy of reorganization of the outer sphere is smaller than that of the inner sphere. Using a large bias potential it sho