Preliminary results arc reported of a Monte Carlo trajectory study of intramolecular vibrational ener\_w relaxation in a model of benzene. Very little relaxation 1s found to occur on d picosecond timeswle. The rate of intramolecular wbrational energy relaxation appears to be dependent upon the natur
Intramolecular vibrational relaxation in 1,4 dioxane
โ Scribed by Kulp, Thomas; Ruoff, Rodney; Stewart, George; McDonald, J. D.
- Book ID
- 120443211
- Publisher
- American Institute of Physics
- Year
- 1984
- Tongue
- English
- Weight
- 722 KB
- Volume
- 80
- Category
- Article
- ISSN
- 0021-9606
- DOI
- 10.1063/1.446666
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๐ SIMILAR VOLUMES
By separating the pure quantuin mechanical dephasing of an initial vibrational nonstationary state from irreversible vibrational decay, recent progress in the theory of electronic relasation processes is immediateIy utilized to describe various types of intramolecular vibrational rcka?ion phenomena.
The pennittivity (Cl) and cLie1ectri.c loss ( ") have been measured at 9.945 GHz for several substituted anilines in cyclohemne and 1:4 dioxane at 35'C. The static pennittivity (8,) at 300 KHZ and hi& frequency limiting permittivity (S,) have also been measured at 35'C. The dielectric data have been