𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Intramolecular reductive cyclization of an enone–aldehyde: a new approach to the synthesis of (±)-majusculone

✍ Scribed by Hsu, Day-Shin; Juo, Bing-Chiuan

Book ID
118749462
Publisher
Elsevier Science
Year
2013
Tongue
French
Weight
752 KB
Volume
54
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Total synthesis of coronafacic acid thro
Total synthesis of coronafacic acid through 6-endo-trig mode intramolecular cyclization of an enone-aldehyde to a hydrindanone using samarium(II) iodide
✍ Masakazu Sono; Atsuko Hashimoto; Katsuyuki Nakashima; Motoo Tori 📂 Article 📅 2000 🏛 Elsevier Science 🌐 French ⚖ 124 KB

Coronafacic acid has been synthesized from a hydrindanone prepared by a 6-endo-trig mode cyclization reaction of the enone-aldehyde with samarium(II) iodide. The stereochemistry of the hydrindanone was controlled by the coordinated samarium species resulting in cis in respect of the hydroxyl group a