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Intramolecular reactions in the oxindole series

โœ Scribed by E. Wenkert; Th. L. Reid

Book ID
112731084
Publisher
Springer
Year
1954
Tongue
English
Weight
202 KB
Volume
10
Category
Article
ISSN
1420-682X

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Solid phase intramolecularHeck couplingallows the syothesisof 2-oxindoles. Additional diversityis introducedinfo the moleculeby reductiveatkylationprior to the Heck cyclisationarrdatso by conjugateadditionof a varietyof nucleophilesontothe cyctisedproductprior to cleavage. 01997 Elsevier ScienceLtd.

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AS the number and variety of established indole alkaloid structures increase, it becomes more and more apparent that many of the structural types derive by varying modes of cyclization of natural intermediates in which certain reactive sites have been brought to specific oxidation levels b . In such