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Intramolecular oxidative diels-alder reaction of n-sorbyl-l-proline acylhydrazides

โœ Scribed by Tuvia Sheradsky; Jenja Milvitskaya; Ithamar E. Pollak


Book ID
104212827
Publisher
Elsevier Science
Year
1991
Tongue
French
Weight
194 KB
Volume
32
Category
Article
ISSN
0040-4039

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Stereocontrol of the Intramolecular Diel
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## Abstract A novel approach for __exo__/__endo__ stereocontrol of intramolecular Dielsโˆ’Alder reactions is described. Substrates carrying a hydroxymethyl group attached to the diene and an ester group attached to the dienophile participate in hydrogen bonding in the transition state. This nonโ€coval