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Diastereofacial selectivity in intramolecular diels-alder reactions of chiral triene-n-acyloxazolidones

✍ Scribed by David A. Evans; Kevin T. Chapman; John Bisaha


Publisher
Elsevier Science
Year
1984
Tongue
French
Weight
247 KB
Volume
25
Category
Article
ISSN
0040-4039

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✦ Synopsis


Excellent diasterofacial selection has been observed in asymmetric Diels-Alder cycloadditions of E,E-triene-imides 3 and 6.


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Diastereofacial selectivity in the Diels
✍ Guido Galley; Clemens MΓΌgge; Peter G. Jones; Michael PΓ€tzel πŸ“‚ Article πŸ“… 1995 πŸ› Elsevier Science 🌐 English βš– 307 KB

The effect of temperature, catalyst and pressure on the outcome of the Diels-Alder reaction of 5(S)-E-5,6-O-isopropyliden-hex-3-en-2-one with cyclopentadiene was investigated. All four possible Diels-Alder adducts were isolated and characterized on the basis of single crystal X-ray analysis and NMR