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A novel strategy for regio- and stereocontrol in [4 + 2] cycloadditions. Intramolecular diels-alder reaction of a sllyl acetal triene

✍ Scribed by Donald Craig; John C. Reader


Publisher
Elsevier Science
Year
1990
Tongue
French
Weight
322 KB
Volume
31
Category
Article
ISSN
0040-4039

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✍ Hoffmann, H. M. R. ;Vathke-Ernst, Heidrun 📂 Article 📅 1981 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 457 KB 👁 1 views

4Methyl-3-penten-2-01 (1) and cyclopentadiene react in an acidic two phase system at 0°C to form allylcyclopentenols 2 and norbornenylcarbinols 4. At 50°C and under similar conditions, 2 as well as 4 are equilibrated to allylcyclopentadienes 3, bicyclic olefins 5 and 6 , and tricyclic ether 7. With