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Tandem Oxidative Dearomatization/Intramolecular Diels–Alder Reaction for Construction of the Tricyclic Core of Palhinine A

✍ Scribed by Zhao, Changgui; Zheng, Huaiji; Jing, Peng; Fang, Bowen; Xie, Xingang; She, Xuegong

Book ID
118060179
Publisher
American Chemical Society
Year
2012
Tongue
English
Weight
573 KB
Volume
14
Category
Article
ISSN
1523-7060

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A tandem oxidative dearomatization/intra
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✍ Vishwakarma Singh; Pravin Bhalerao; Shaikh M. Mobin 📂 Article 📅 2010 🏛 Elsevier Science 🌐 French ⚖ 346 KB

A short and efficient route to tricyclic ring system containing bridged bicyclo[2.2.2]octanone annulated with a lactone ring present in the maoecrystal is described. In-situ generation of spiroepoxycyclohexa-2,4-dienone and intramolecular cycloaddition are the key features of our approach.