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Tandem Phenolic Oxidative Amidation−Intramolecular Diels−Alder Reaction: An Approach to the Himandrine Core

✍ Scribed by Liang, Huan; Ciufolini, Marco A.


Book ID
126931793
Publisher
American Chemical Society
Year
2010
Tongue
English
Weight
724 KB
Volume
12
Category
Article
ISSN
1523-7060

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Intramolecular diels-alder reactions of
✍ Daniel L. Comins; Abdul H. Abdullah; Roy K. Smith 📂 Article 📅 1983 🏛 Elsevier Science 🌐 French ⚖ 181 KB

In refluxing decalin P-alkenyl-1-alkoxycarbonyl-1,2\_dihydropyridines undergo an intramolecular Diels-Alder reaction to provide novel polycyclic compounds. The cis-decahydroquinoline ring system can be prepared from the appropriate Diels-Alder product utilizing a ring-opening reverse Mannich reactio