๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

Intramolecular isotope effect in dissociations

โœ Scribed by F. Fiquet-Fayard; M. Sizun; H. Abgrall


Publisher
Elsevier Science
Year
1976
Tongue
English
Weight
529 KB
Volume
37
Category
Article
ISSN
0009-2614

No coin nor oath required. For personal study only.

โœฆ Synopsis


We discuss the dissociatian of a molecule HXD, when the dissociation occurs OT: ;t repulsive surfLm with a single saddle point. We cnlvulate the order of magnitude of the intramolecular isotope effect, and find it in apeemeat uith espcrimcnbl observations.


๐Ÿ“œ SIMILAR VOLUMES


Intramolecular isotope effect in laser m
โœ A.J. Colussi; S.W. Benson; R.J. Hwang; J.J. Tiee ๐Ÿ“‚ Article ๐Ÿ“… 1977 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 488 KB

The ratio r = [lICl]/[ DCI], for the decomposition of ethyl Wt chloride, CH2DCII2CI, induced by mtcn\c CO2 h\cr ~UIIIS, has been mummd under dlffcrcnt cxperimcntal condition\. Changes in be;ml cncrgy, bc;mr peomctry. rohtlon,ll he% irradiatton tanc and pressure have no discernible cffcct 01' r. It i

Intramolecular hydrogen isotope effect i
โœ William E. Farneth; Thomas L. Beck ๐Ÿ“‚ Article ๐Ÿ“… 1983 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 332 KB

The thermal unimolecular decomposition of diethyl carbonate-1,1,1,2,2-d5 has been examined in the high-pressure-limiting region. The observed chemistry is consistent with a simple, competitive two-channel model: The intramolecular isotope effect k H / k D has been determined, and the relative Arrhe

Intramolecular isotopic effect in the py
โœ P. J. Papagiannakopoulos; S. W. Benson ๐Ÿ“‚ Article ๐Ÿ“… 1982 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 596 KB

The thermal decomposition of deuterated ethyl chloride CHzDCHzCl was studied in a static system in the pressure range of 0.1-26 torr, and the Arrhenius expression for the overall decomposition at the high-pressure limit and in the temperature range of 670-1100 K was found to be k , = 1013.33\*0.10 e