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Intramolecular dephasing in pyrazine: deuterium isotope effect and further tests of theory

โœ Scribed by Peter M. Felker; Ahmed H. Zewail

Publisher
Elsevier Science
Year
1986
Tongue
English
Weight
895 KB
Volume
128
Category
Article
ISSN
0009-2614

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The kinetics of the gas phase intramolecular elimination of isobutene from 2-d1-triisobutylaluminum and the deuterium isotope effect in reactions involving cyclic transition states
โœ Kurt W. Egger ๐Ÿ“‚ Article ๐Ÿ“… 1969 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 654 KB

The intramolecular elimination of isobutene from 2-d,-triisobutylaluminum has been studied in the gas phase for temperatures ranging between 102.4 and 184.6'C. The reaction is apparently homogeneous and obeys the first order rate law, yielding the following Arrhenius relationship: log kelim (sec-')