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Intramolecular Homolytic Displacements. 30. Functional Decarbonylative Transformations of Aldehydes via Homolytically Induced Decomposition of Unsaturated Peroxyacetals

โœ Scribed by Degueil-Castaing, Marie; Moutet, Laurent; Maillard, Bernard


Book ID
126277630
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
116 KB
Volume
65
Category
Article
ISSN
0022-3263

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ChemInform Abstract: Functional Transfor
โœ L. Moutet; D. Bonafoux; M. Degueil-Castaing; B. Maillard ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 32 KB ๐Ÿ‘ 2 views

The induced decomposition of the unsaturated peroxy acetal (IV) in the presence of CCl 4 or ethyl iodoacetate leads to its chloro-or iododecarbonylation with good yields. This reaction is also applied to the monoperoxy ketal (VIII) and the diperoxy ketal (X) of cyclohexanone. The title decomposition