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ChemInform Abstract: Intramolecular Homolytic Displacements. Part 30. Functional Decarbonylative Transformations of Aldehydes via Homolytically Induced Decomposition of Unsaturated Peroxyacetals.

✍ Scribed by Marie Degueil-Castaing; Laurent Moutet; Bernard Maillard

Publisher: John Wiley and Sons
Year: 2000
Weight: 33 KB
Volume: 31
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200044033

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The induced decomposition of the unsaturated peroxy acetal (IV) in the presence of CCl 4 or ethyl iodoacetate leads to its chloro-or iododecarbonylation with good yields. This reaction is also applied to the monoperoxy ketal (VIII) and the diperoxy ketal (X) of cyclohexanone. The title decomposition