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Intramolecular Electronic Interactions in Conjugated Ferrocene−π-Extended-Tetrathiafulvalene Donor-π-Donor Molecular Hybrids

✍ Scribed by Liu, Sheng-Gao; Pérez, Ignacio; Martín, Nazario; Echegoyen, Luis

Book ID
111904340
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
191 KB
Volume
65
Category
Article
ISSN
0022-3263

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Strong π-electron donors based on a self-rigidified 2,2′-bi(3,4-ethylenedioxy)thiophene–tetrathiafulvalene hybrid π-conjugated system
✍ Philippe Leriche; Mathieu Turbiez; Vincent Monroche; Pierre Frère; Philippe Blan 📂 Article 📅 2003 🏛 Elsevier Science 🌐 French ⚖ 281 KB

Strong p-donors based on the association of TTF and 2,2%-bi(3,4-ethylenedioxy)thiophene conjugating unit have been synthesised; optical and an X-ray data show that intramolecular interactions lead to full rigidification of the conjugated system.