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Strong π-electron donors based on a self-rigidified 2,2′-bi(3,4-ethylenedioxy)thiophene–tetrathiafulvalene hybrid π-conjugated system

✍ Scribed by Philippe Leriche; Mathieu Turbiez; Vincent Monroche; Pierre Frère; Philippe Blanchard; Peter J. Skabara; Jean Roncali


Book ID
104252784
Publisher
Elsevier Science
Year
2003
Tongue
French
Weight
281 KB
Volume
44
Category
Article
ISSN
0040-4039

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✦ Synopsis


Strong p-donors based on the association of TTF and 2,2%-bi(3,4-ethylenedioxy)thiophene conjugating unit have been synthesised; optical and an X-ray data show that intramolecular interactions lead to full rigidification of the conjugated system.