Hybrid Molecular Materials Based upon Magnetic Polyoxometalates and Organic π-Electron Donors: Syntheses, Structures, and Properties of Bis(ethylenedithio)tetrathiafulvalene Radical Salts with Monosubstituted Keggin Polyoxoanions

Hybrid Molecular Materials Based upon Or

Hybrid Molecular Materials Based upon Organic π-Electron Donors and Inorganic Metal Complexes. Conducting Salts of Bis(ethylenediseleno)tetrathiafulvalene (BEST) with the Octahedral Anions Hexacyanoferrate(III) and Nitroprusside

✍ Miguel Clemente-León; Eugenio Coronado; José R. Galán-Mascarós; Carlos Giménez-S 📂 Article 📅 2002 🏛 Elsevier Science 🌐 English ⚖ 413 KB

The synthesis, structure and physical characterization of three new radical salts formed by the organic donor bis(ethylenediseleno)tetrathiafulvalene (BEDS-TTF or BEST) and the paramagnetic hexacyanoferrate(III) anion [Fe(CN) 6 ] 3À or the photochromic nitroprusside anion [Fe(CN) 5 NO] 2À are report