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Intramolecular Diels−Alder Reactions of Decatrienoates: Remote Stereocontrol and Conformational Activation 1

✍ Scribed by Kim, Pilho; Nantz, Michael H.; Kurth, Mark J.; Olmstead, Marilyn M.


Book ID
127389366
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
81 KB
Volume
2
Category
Article
ISSN
1523-7060

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✍ Tietze, Lutz F. ;Utecht, Jens 📂 Article 📅 1992 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 542 KB

Azabutadienes f Isoxazoles f Tetrahydropyridines 1 Diels-Alder reactions / Sequential transformations Condensation of aldehydes 1 ae with 5-amino-3-methylisoxazole (4) gives the corresponding imines 5a-e with a 2-aza-1,3-butadiene moiety, which cyclize selctively, e.g. 5a to form the trans-fused tet