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Intramolecular Diels—Alder Reaction of 1,7,9-Decatrienoates Catalyzed by Indium(III) Trifluoromethanesulfonate in Aqueous Media.

✍ Scribed by Hikaru Yanai; Akio Saito; Takeo Taguchi

Publisher: John Wiley and Sons
Year: 2005
Weight: 24 KB
Volume: 36
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200545164

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Abstract4 A mixture of tetrachiral deca-1,7E,9-triene 2 and its 72 isomer 2 was prepared from D-glucose by the use of two Wittig olefination reactions. When 5 or 6 were subjected to intramolecular Diels-Alder reaction un'-er Thermal conditions the same, cis-fused octahydronaphtalene enantiomer 9 was