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Intramolecular Diels-Alder reactions of ethyl 2,4,9-decatrienoate and 2,4,10-undecatrienoate

✍ Scribed by Yi-Tsong Lin; K.N. Houk


Book ID
104228977
Publisher
Elsevier Science
Year
1985
Tongue
French
Weight
187 KB
Volume
26
Category
Article
ISSN
0040-4039

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A bridged triptycene-intramolecular diel
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A bridged triptycene was obtained by intramolecular cycloaddition reaction of 16,19-dimethoxy[ZJ (9,lO)anthracenomparacycIophane followed by acid-cotoiyzed elimination of methanol. Internal strain in this molecule was disclosed by X-ray crystallographic analysis. Lice and C. G.