The positions of conformational equiliirium in disubstituted arene chromium tricarbonyl complexes, i.e. alkylanisole chromium tricmbonyl complexes and alkylbenzoate chromium tricarbonyl complexes, have been determined by 'H N M R spectroscopy. It has been found that the donor effect is the dominant
Intramolecular CO ⋯ H interaction in Arene(tricarbonyl)-chromium complexes
✍ Scribed by I. V. Bodrikov; I. I. Grinval’d; A. N. Artemov; L. I. Bazhan; I. Yu. Kalagaev
- Book ID
- 111460391
- Publisher
- Springer
- Year
- 2010
- Tongue
- English
- Weight
- 146 KB
- Volume
- 80
- Category
- Article
- ISSN
- 1070-3632
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1,5-Remote diastereoselection on the acyclic systems is achieved by diastereoselective Cr(C0j3 complexation, chirality transfer in acyclic system and following stereoselective alkylation at the benzylic position. One of the most exciting challenges in the synthetic methodology is control of stereoch