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Arene−Chromium Tricarbonyl Complexes in the Pauson−Khand Reaction

✍ Scribed by Rosillo, Marta; Domínguez, Gema; Casarrubios, Luis; Pérez-Castells, Javier

Book ID
127360135
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
113 KB
Volume
70
Category
Article
ISSN
0022-3263

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Transition metal alkyne complexes: the P
Transition metal alkyne complexes: the Pauson–Khand reaction
✍ Young Keun Chung 📂 Article 📅 1999 🏛 Elsevier Science 🌐 English ⚖ 859 KB

The Pauson-Khand reaction (PKR) is a cocyclization of alkynes with alkenes and carbon monoxide by dicobalt octacarbonyl leading to cyclopentenones and has become one of the most useful methods for the synthesis of cyclopentenone. However, most of the known PKRs were stoichiometric and slow reactions