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Intramolecular Charge Interaction in the Radical Cations and Dications of Conjugated Tetrathiafulvalene Dimers.

✍ Scribed by Masahiko Iyoda; Masashi Hasegawa; Jun-ichi Takano; Kenji Hara; Yoshiyuki Kuwatani

Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
33
Category
Article
ISSN
0931-7597

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πŸ“œ SIMILAR VOLUMES

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Intramolecular Ο€-Stacking Interactions of Bridged Bis-p-Phenylenediamine Radical Cations and Diradical Dications: Charge-Transfer versus Spin-Coupling
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Scheme 1. Dimeric doubly three-carbon-bridged p-phenylene diamines. Scheme 2. Three conformations of dimeric diradical dications 1 2+ .

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Direct Observation of Mixed-Valence and Radical Cation Dimer States of Tetrathiafulvalene in Solution at Room Temperature: Association and Dissociation of Molecular Clip Dimers Under Oxidative Control
✍ Pinn-Tsong Chiang; Nai-Chia Chen; Chien-Chen Lai; Sheng-Hsien Chiu πŸ“‚ Article πŸ“… 2008 πŸ› John Wiley and Sons 🌐 English βš– 390 KB

## Abstract We have observed the mixed‐valence and radical cation dimer states of a glycoluril‐based molecular clip with tetrathiafulvalene (TTF) sidewalls at low concentration (1β€…mM) at room temperature. This molecular clip has four consecutive anodic steps in its cyclic voltammogram, which sugges