Intramolecular π-Stacking Interactions of Bridged Bis-p-Phenylenediamine Radical Cations and Diradical Dications: Charge-Transfer versus Spin-Coupling

✍ Scribed by Almaz S. Jalilov; Prof. Stephen F. Nelsen; Dr. Ilia A. Guzei; Dr. Qin Wu

• Publisher: John Wiley and Sons
• Year: 2011
• Tongue: English
• Weight: 415 KB
• Volume: 123
• Category: Article
• ISSN: 0044-8249
• DOI: 10.1002/ange.201102629

✦ Synopsis

Scheme 1. Dimeric doubly three-carbon-bridged p-phenylene diamines.

Scheme 2. Three conformations of dimeric diradical dications 1 2+ .