Intramolecular C–H insertion in ring-expanded N-heterocyclic carbenes
✍ Scribed by Robert S. Holdroyd; Michael J. Page; Mark R. Warren; Michael K. Whittlesey
- Book ID
- 108285776
- Publisher
- Elsevier Science
- Year
- 2010
- Tongue
- French
- Weight
- 216 KB
- Volume
- 51
- Category
- Article
- ISSN
- 0040-4039
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📜 SIMILAR VOLUMES
The alkylidene carbene generated by chloromethylenation / or-elimination of 1 proceeds with a high degree of selectivity for methoxy C-H insertion over methine insertion, to give 2. The carbene generated with trimethylsilyldiazomethane results in an approximately 1:1 mixture of 2 and 3.
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v
## Abstract The performances of a number of Rh^I^ and Ir^I^ complexes of type [M(NHC)(COD)Cl] in the transfer hydrogenation of ketones were tested under a variety of reaction conditions, and with a variety of substrates, allowing comparison of Rh‐ and Ir‐NHC complexes, and also comparison of the in