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Novel Expanded Ring N-Heterocyclic Carbenes: Free Carbenes, Silver Complexes, And Structures

✍ Scribed by Iglesias, Manuel; Beetstra, Dirk J.; Knight, James C.; Ooi, Li-Ling; Stasch, Andreas; Coles, Simon; Male, Louise; Hursthouse, Michael B.; Cavell, Kingsley J.; Dervisi, Athanasia; Fallis, Ian A.


Book ID
120163683
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
291 KB
Volume
27
Category
Article
ISSN
0276-7333

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Organometallic chemistry of silver and c
✍ Polly L. Arnold πŸ“‚ Article πŸ“… 2002 πŸ› John Wiley and Sons 🌐 English βš– 164 KB πŸ‘ 1 views

## Abstract The only stable organometallic carbene complexes of silver and copper are those of N‐heterocyclic carbenes, since formally these robust divalent carbon ligands bind only by a Οƒ donor interaction to the metal. A survey of the range of complexes that have now been reported is presented. Β©