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Expanded ring and functionalised expanded ring N-heterocyclic carbenes as ligands in catalysis

✍ Scribed by Binobaid, Abeer; Iglesias, Manuel; Beetstra, Dirk J.; Kariuki, Benson; Dervisi, Athanasia; Fallis, Ian A.; Cavell, Kingsley J.

Book ID
120163711
Publisher
Royal Society of Chemistry
Year
2009
Tongue
English
Weight
479 KB
Volume
35
Category
Article
ISSN
1477-9226

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Donor-Functionalised Expanded Ring N-Heterocyclic Carbenes: Highly Effective Ligands in Ir-Catalysed Transfer Hydrogenation
✍ Abeer Binobaid; Manuel Iglesias; Dirk Beetstra; Athanasia Dervisi; Ian Fallis; K πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons 🌐 English βš– 243 KB πŸ‘ 1 views

## Abstract The performances of a number of Rh^I^ and Ir^I^ complexes of type [M(NHC)(COD)Cl] in the transfer hydrogenation of ketones were tested under a variety of reaction conditions, and with a variety of substrates, allowing comparison of Rh‐ and Ir‐NHC complexes, and also comparison of the in