Intramolecular catalysis in photolysis of N-nitrosamines. An oxidative decarboxylation of α-amino acids.
✍ Scribed by Y.L. Chow
- Publisher
- Elsevier Science
- Year
- 1965
- Tongue
- French
- Weight
- 242 KB
- Volume
- 6
- Category
- Article
- ISSN
- 0040-4039
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📜 SIMILAR VOLUMES
## Abstract A novel low toxic, water‐ and air‐tolerated method under mild and neutral conditions for the title reaction is developed.
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v
Sumnary: a-Hydroxycarboxylic acids (I\_) reacted with N-sulfinylanilines (2) to yive the corresponding a-hydroxyanilides (2) in quantitative yields under mild condition: the reaction appears to involve intermolecular catalysis by the carboxylic acid moiety and intramolecular catalysis by the hydroxy