✦ LIBER ✦

New facile synthesis of α-hydroxyamides: Intermolecular and intramolecular catalysis in the reaction of α-hydroxycarboxylic acids with N-sulfinylamines.

✍ Scribed by Jai Moo Shin; Yong Hae Kim

Publisher: Elsevier Science
Year: 1986
Tongue: French
Weight: 239 KB
Volume: 27
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)84412-3

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✦ Synopsis

Sumnary: a-Hydroxycarboxylic acids (I_) reacted with N-sulfinylanilines (2) to yive the corresponding a-hydroxyanilides (2) in quantitative yields under mild condition: the reaction appears to involve intermolecular catalysis by the carboxylic acid moiety and intramolecular catalysis by the hydroxyl group.

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