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Intersystem crossing to both ligand-localized and charge-transfer excited states in mononuclear and dinuclear ruthenium(II) diimine complexes

✍ Scribed by Shaw, John R.; Webb, Ralph T.; Schmehl, Russell H.


Book ID
120267246
Publisher
American Chemical Society
Year
1990
Tongue
English
Weight
982 KB
Volume
112
Category
Article
ISSN
0002-7863

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We have studied the interfacial electron-transfer dynamics on TiO(2) film sensitized with synthesized ruthenium(II)-polypyridyl complexes--[Ru(II)(bpy)(2)(L(1))] (1) and [Ru(II)(bpy)(L(1))(L(2))] (2), in which bpy=2,2'-bipyridyl, L(1)=4-[2-(4'-methyl-2,2'-bipyridinyl-4-yl)vinyl]benzene-1,2-diol, and