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Solvent dependence of metal-to-ligand charge-transfer transitions. Evidence for initial electron localization in MLCT excited states of 2,2'-bipyridine complexes of ruthenium(II) and osmium(II)

✍ Scribed by Kober, Edward M.; Sullivan, B. Patrick; Meyer, Thomas J.


Book ID
120156310
Publisher
American Chemical Society
Year
1984
Tongue
English
Weight
935 KB
Volume
23
Category
Article
ISSN
0020-1669

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## Abstract The resonance Raman and time‐resolved resonance Raman (TR^3^) spectra of ruthenium(II) complexes containing the asymmetric (RR)(5‐methyl‐2,2′‐bipyridine) ligand, Ru(5‐mmb), and its methyl‐deuterated analogue, Ru(5‐d~3~‐mmb), are reported. The spectra are compared to those of tris(2, 2′‐