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Intermode energy transfer in vibrationally excited O3

โœ Scribed by Kin-Kwok Hui; David I. Rosen; Terrill A. Cool

Publisher
Elsevier Science
Year
1975
Tongue
English
Weight
321 KB
Volume
32
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

The laser excited fluorexence methcd has been employed to determine the rate constants for vibrAtiona rcLsation of the OS @lo), O3 (100) and O3 (001) levels at 298 K. The fluorescence observations from the 03 (010) Ieve1 provide direct mGwlremZ;nts~of Ilie rate for int+mcdc vibtitional enor$' trnnsfcr from tire couptsd wI md vD mc-ddcs to the uz' mode. The slowness of this ~roceu: indicates the likelihood that thz U, and/or ZJ~ modes (rather than the ~2 mode) play a predominant role in the Lser enhanced reaction between 04 and NO at 298 K.

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