✦ LIBER ✦

Production of electronically excited iodine monofluoride by energy transfer from vibrationally excited hydrogen fluoride

✍ Scribed by G.W. Tregay; J.W. Raymonda; H.M. Thompson; T.E. Furner

Publisher: Elsevier Science
Year: 1986
Tongue: English
Weight: 430 KB
Volume: 123
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(86)80043-4

No coin nor oath required. For personal study only.

✦ Synopsis

IF (B'II,+ -+ X'Z+ ) cbemiluminescence was observed in flame (T> 2000 K) and flow tube (T cl000 K) experiments using the F2, I,, and H, reactants diluted with helium. The emission with hydrogen present is 70 times greater than for I, + Fz alone. The dependence of the emission Intensity on operating parameters Indicates that the primary source of IF electromc excitations is wbrationally excited HF.