## Abstract For Abstract see ChemInform Abstract in Full Text.
Intermediates of Asymmetric Oxidation Processes Catalyzed by Vanadium(V) Complexes
โ Scribed by K. P. Bryliakov; E. P. Talsi
- Book ID
- 111542699
- Publisher
- Springer
- Year
- 2003
- Tongue
- English
- Weight
- 156 KB
- Volume
- 44
- Category
- Article
- ISSN
- 0023-1584
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๐ SIMILAR VOLUMES
Vanadium catalysts bearing (+)-ketopinic acid-based chiral hydroxamic acids as constituent ligands are investigated in the asymmetric epoxidation of allylic alcohols. Chiral ligands lacking an N-substituent and those having a bulkier aryl group in the bornane skeleton provided better selectivity.
Asymmetric Oxidation of Dithioacetals and Dithioketals Catalyzed by a Chiral Vanadium Complex. -The asymmetric oxidation of dithioacetals [cf. (I), (III)] and dithioketals [cf. (V)] using 30% aqueous H 2 O 2 in the presence of VO(acac) 2 and a chiral ligand derived from amino alcohol and salicylald