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Asymmetric Oxidation of Sulfides Catalyzed by Vanadium(IV) Complexes of Dibromo- and Diiodo-Functionalized Chiral Schiff Bases

โœ Scribed by Aiping GAO; Mei WANG; Dongping WANG; Lu ZHANG; Haibin LIU; Wei TIAN; Licheng SUN

Publisher
Elsevier Science
Year
2006
Weight
260 KB
Volume
27
Category
Article
ISSN
1872-2067

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โœ Konstantin P. Bryliakov; Evgenii P. Talsi ๐Ÿ“‚ Article ๐Ÿ“… 2007 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 551 KB

Sulfoxidation catalysts generated in situ from titanium(IV) isopropoxide and enantiopure Schiff bases promote the enantioselective oxidation of alkyl aryl sulfides to the corresponding sulfoxides at low catalyst loadings (<1 mol%), 30% aqueous hydrogen peroxide being the terminal oxidant. Upon scree