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Asymmetric oxidation of sulfides with H2O2 catalyzed by titanium complexes of Schiff bases bearing a dicumenyl salicylidenyl unit

✍ Scribed by Ying Wang; Mei Wang; Lin Wang; Yu Wang; Xiuna Wang; Licheng Sun


Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
173 KB
Volume
25
Category
Article
ISSN
0268-2605

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## Abstract Catalytic properties of a series of chiral (pyrrolidine salen)Mn(III) complexes for asymmetric oxidation of aryl methyl sulfides were evaluated. Moderate activity, good chemical selectivity and low enantioselectivity were attained with iodosylbenzene as a terminal oxidant. Enantioselect