The mono-to tetra-hydrates and hexahydrates of Na+, Mg\*' and Ai3+ have been taken as examples to investigate to what extend the interactions in water-metal complexes can be replaced by sums of water-water and water-ion two-body interactions. It is found that the quality of the approximation of pair
✦ LIBER ✦
Interactions in a phosphate—water—cation system
✍ Scribed by H. Berthod; A. Pullman
- Publisher
- Elsevier Science
- Year
- 1977
- Tongue
- English
- Weight
- 306 KB
- Volume
- 46
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
✦ Synopsis
SCI' ab mitlo study of the system dimethylphosph,tfe anron-WJtcr--NJ* m the supern~olecule approach shows the competitlvlty of the through-water binding of NJ* to a phosphodlc\ter hnkap with its dmxt utteraction. Confirm,ttion of :hls ,Guation IP seen in J number of crystal structures of mono-and ohgonucleotldes.
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