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Stable β Turns of Tripeptides in Water through Cation–π Interactions

✍ Scribed by Damien Barbaras; Karl Gademann

Publisher: John Wiley and Sons
Year: 2008
Tongue: English
Weight: 352 KB
Volume: 9
Category: Article
ISSN: 1439-4227
DOI: 10.1002/cbic.200800344

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## Abstract The effects of N‐methylation and chain length on a cation–π interaction have been investigated within the context of a β‐hairpin peptide. Significant enhancement of the interaction and structural stabilization of the hairpin have been observed upon Lys methylation. Thermodynamic analysi