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Interaction of α-TiCl3with organoaluminium compounds and its correlation with propylene polymerization

✍ Scribed by B. V. Kokta; R. G. Raj

Publisher
Springer
Year
1990
Tongue
English
Weight
211 KB
Volume
23
Category
Article
ISSN
0170-0839

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✦ Synopsis

The kinetics of the interaction between the catalyst components of a Ziegler-Natta sterospecific system formed by TiCl 3 and AIEt in heptane was studied.

The experimental results

show Chat the rate of propylene polymerization is influenced by the rate of the interaction, activation energy, and the efficiency of interaction.

📜 SIMILAR VOLUMES

Interaction of α-TiCl3with organoalumini
Interaction of α-TiCl3with organoaluminium compounds and its correlation with propylene polymerization
✍ B. V. Kokta; R. G. Raj 📂 Article 📅 1990 🏛 Springer 🌐 English ⚖ 233 KB

The characterization of polymer system by means of interaction reaction between the catalyst components of a Ziegler-Natta stereospecific system formed by TiCl 3 and AIEt 3 in heptane was carried out. The experimental results show that the formation and decay of the active centers are interdependent

Polymerization of 4-methylpentene-1 and
Polymerization of 4-methylpentene-1 and its copolymerization with propylene on the TiCl3 + (C2H5)2AlCl complex catalyst
✍ V.Sh. Shteinbak; V.V. Amerik; F.I. Yakobson; Yu.V. Kissin; D.V. Ivanyukov; B.A. 📂 Article 📅 1975 🏛 Elsevier Science 🌐 English ⚖ 720 KB

The main kinetic laws governing 4-methylpentene-I (MP) polymerization and copolymerization with propylene (P) on the catalytic system TiCI 3 + (C2Hs)gAIC1 between 30 and 70 ° were studied. The MP homopolymerization is kinetically first-order in monomer and TiCl> The effective activation energy is 8'