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Polymerization of 4-methylpentene-1 and its copolymerization with propylene on the TiCl3 + (C2H5)2AlCl complex catalyst

✍ Scribed by V.Sh. Shteinbak; V.V. Amerik; F.I. Yakobson; Yu.V. Kissin; D.V. Ivanyukov; B.A. Krentsel

Publisher
Elsevier Science
Year
1975
Tongue
English
Weight
720 KB
Volume
11
Category
Article
ISSN
0014-3057

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✦ Synopsis

The main kinetic laws governing 4-methylpentene-I (MP) polymerization and copolymerization with propylene (P) on the catalytic system TiCI 3 + (C2Hs)gAIC1 between 30 and 70 Β° were studied. The MP homopolymerization is kinetically first-order in monomer and TiCl> The effective activation energy is 8'5 kcal/mole. The active site concentrations in MP polymerization at various temperatures were evaluated. The copolymerization constants were determined: for P r, = 6-44 _+ 05: for MP r2 = 0.31 + 0"05. The structure of the copolymers was studied, some of their properties are described.

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