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Interaction of α-TiCl3with organoaluminium compounds and its correlation with propylene polymerization

✍ Scribed by B. V. Kokta; R. G. Raj

Publisher
Springer
Year
1989
Tongue
English
Weight
192 KB
Volume
22
Category
Article
ISSN
0170-0839

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Interaction of α-TiCl3with organoalumini
Interaction of α-TiCl3with organoaluminium compounds and its correlation with propylene polymerization
✍ B. V. Kokta; R. G. Raj 📂 Article 📅 1990 🏛 Springer 🌐 English ⚖ 233 KB

The characterization of polymer system by means of interaction reaction between the catalyst components of a Ziegler-Natta stereospecific system formed by TiCl 3 and AIEt 3 in heptane was carried out. The experimental results show that the formation and decay of the active centers are interdependent

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The kinetics of the interaction between the catalyst components of a Ziegler-Natta sterospecific system formed by TiCl 3 and AIEt in heptane was studied. ## The experimental results show Chat the rate of propylene polymerization is influenced by the rate of the interaction, activation energy, and

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The main kinetic laws governing 4-methylpentene-I (MP) polymerization and copolymerization with propylene (P) on the catalytic system TiCI 3 + (C2Hs)gAIC1 between 30 and 70 ° were studied. The MP homopolymerization is kinetically first-order in monomer and TiCl> The effective activation energy is 8'