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Insertion of Carbon Dioxide into Main-Group Complexes: Formation of the [N(CO2)3]3− Ligand

✍ Scribed by Diane A. Dickie; Marie V. Parkes; Richard A. Kemp


Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
327 KB
Volume
120
Category
Article
ISSN
0044-8249

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tert-Butyl isocyanide reacts with the m 3 -alkylidyne complex [{TiCp\*(m-O)} 3 (m 3 -CH)] (1, Cp\* h 5 -C 5 Me 5 ) to give a single insertion into a m 3 -carbon ± titanium bond and the formation of the new derivative [{TiCp\* (m-O)} 3 (m 3 -h 2 -HCCNtBu)] (3). Similar reactions of 2,6-Me 2 C 6 H 3 N