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Initial adduct formation by 1,4-benzoquinones in liquid ammonia to give 4-amino-4-hydroxycyclohexa-2,5-dienones and 3,6-diamino-3,6-dihydroxycyclohexa-1,4-dienes

✍ Scribed by Chudek, John A.; Foster, Roy; Reid, Francis J.

Book ID: 120174556
Publisher: Royal Society of Chemistry
Year: 1984
Tongue: English
Weight: 546 KB
Volume: 2
Category: Article
ISSN: 1472-779X
DOI: 10.1039/P29840000287

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## Abstract 2‐Amino‐3‐methylimidazo[4,5‐f]quinoline (IQ) and 2‐amino‐1‐methyl‐6‐phenylimidazo[4,5‐__b__)]pyridine (PhIP) are two members of a family of carcinogenic heterocyclic amines (HAs) found in cooked meats that form DNA adducts after activation to __N__‐acetoxy derivatives. The ability of IQ