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Infrared study of the solid phases of SiH4 and GeH4

โœ Scribed by P. Calvani; C. Ciotti; S. Cunsolo; S. Lupi


Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
339 KB
Volume
75
Category
Article
ISSN
0038-1098

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๐Ÿ“œ SIMILAR VOLUMES


Proton NMR study of molecular motion in
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Proton Zcoman-and dipolar spin-lattice rekxation times and second moments have been measured in polycrystallinc SiH4 at 24 %IHz, between 90 and 3 K. Down to 25 K the classical model for molecular motion appibs; below 25 EC, quantum effects have to be taken into account.

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## Recentty. the absolute values of the H and 19F spio-rot~~on constants in SiH4 , GeH C&F4 wore reported on the basis of n;<4ecular beam measurements. We note here a me 4r; CFQ, SiF4, afd od of determinmg the signs of the spin-rotation constants. Our results show that the proton spin-rotation co