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The sign of the nuclear spin-rotation constants of H in SiH4 and GeH4 and 19F in CF4, SiF4, GeF4

✍ Scribed by H.L. Tigelaar; W.H. Flygare

Publisher: Elsevier Science
Year: 1970
Tongue: English
Weight: 309 KB
Volume: 7
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(70)80301-3

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✦ Synopsis

Recentty. the absolute values of the H and 19F spio-rot~~on constants in SiH4

, GeH C&F4 wore reported on the basis of n;<4ecular beam measurements.

We note here a me 4r; CFQ, SiF4, afd od of determinmg the signs of the spin-rotation constants. Our results show that the proton spin-rotation constants in SiH4 a& G&Q are positive and the 19~ spin-rotation constants in CF4, SiF,, and GeF4 are negative,

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