Infrared spectrum of the benzene-hydrogen fluoride complex in solid argon
โ Scribed by Andrews, Lester; Johnson, Gary L.; Davis, Steven R.
- Book ID
- 120340061
- Publisher
- American Chemical Society
- Year
- 1985
- Tongue
- English
- Weight
- 462 KB
- Volume
- 89
- Category
- Article
- ISSN
- 0022-3654
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๐ SIMILAR VOLUMES
Diatomic fluorine was reacted in a low pressure flame with selenium atoms, generated by a microwave discharge in argon seeded with Se 2, and the products were trapped in solid argon; new infrared absorptions were found at 677.0 and 680.4 cm-l for 8ยฐSe19F and 76selgF, respectively.
Argon/benzene samples were condensed at I Z K with contmuous argon resonance radlatlon Laser excitation af 421 nm produced a weak emlsslon with structure at 19770, 19140 and 18290 cm-l, assrgned to the 'A,,-2E,gemlssron of CBHz Obser\atron of 630 and 1480 cm-' mtervals for the vibrations ~, a (e,,)
An infrared matrix isolation study has been performed for sodium and benzene mixtures in solid argon at 9 K. In contrast with the earlier report, sodium was evidenced to form complexes with benzene. Although the exact nature of the complexes is not certain, ab initio quantum mechanical calculation i