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Infrared spectra of sodium and benzene in solid argon

✍ Scribed by Hack Sung Kim; Kwan Kim

Publisher: Elsevier Science
Year: 1996
Tongue: English
Weight: 396 KB
Volume: 250
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(96)00007-3

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✦ Synopsis

An infrared matrix isolation study has been performed for sodium and benzene mixtures in solid argon at 9 K. In contrast with the earlier report, sodium was evidenced to form complexes with benzene. Although the exact nature of the complexes is not certain, ab initio quantum mechanical calculation indicated clearly that the 1 : 1 Na-C6H 6 complex should be as stable as the 1 : 1 Li-C6H 6 complex. The tentatively assigned peak frequencies for the 1 : 1 Na-C6H 6 complex were also in fair agreement with the theoretical values.

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