✦ LIBER ✦

Infrared spectra of Ca+NO− and Ca+NO−2 in solid argon at 15 K

✍ Scribed by David E. Tevault; Lester Andrews

Publisher: Elsevier Science
Year: 1977
Tongue: English
Weight: 384 KB
Volume: 48
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(77)80224-8

No coin nor oath required. For personal study only.

✦ Synopsis

Calcium atoms have been reacted with NO and NO2 upon condensation at high dilution in argon at 15 K. Infrared absorptions at 1357 and 455 cm-* show appropriate isotopic shifts to be due to @I -O)-and Caf -(NO)-viirations in the Ca%O-species. A strong band at 1244 cm-l is due to YJ of NO; in the Ca?UO; complex_ Recent studies [l-3] of alkali metal atom-nitric oxide matrix reaction products have produced the species MiNO-. The (N-O)-vibration varied from 1352 to 1374 cm-1 depending upon the alkali counterion which was explained in terms of an ionic model of polarizable ion pairs [2]. The alkaline earth metal counter-

📜 SIMILAR VOLUMES

The Raman spectra of (14NO)2 and (15NO)2

The Raman spectra of (14NO)2 and (15NO)2 solids at 20 K

✍ J. R. Durig; M. G. Griffin 📂 Article 📅 1976 🏛 John Wiley and Sons 🌐 English ⚖ 333 KB

ChemInform Abstract: Infrared and EPR Sp

ChemInform Abstract: Infrared and EPR Spectra of F2NO Radicals Stabilized in Solid Argon.

✍ Eugenii Ya. Misochko; Alexander V. Akimov; Ilya U. Goldschleger; Charles A. Wigh 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 29 KB 👁 2 views

Apparent molar heat capacities and volum

Apparent molar heat capacities and volumes of aqueous electrolytes at 298.15 K: Ca(NO3)2, Co(NO3)2, Cu(NO3)2, Mg(NO3)2, Mn(NO3)2, Ni(NO3)2, and Zn(NO3)2

✍ Jan J. Spitzer; Inger V. Olofsson; Prem Paul Singh; Loren G. Hepler 📂 Article 📅 1979 🏛 Elsevier Science 🌐 English ⚖ 374 KB

FTIR spectra of (HF)2 and (HF)3 species

FTIR spectra of (HF)2 and (HF)3 species in solid argon at 12K

✍ Lester Andrews; Gary L. Johnson 📂 Article 📅 1983 🏛 Elsevier Science 🌐 English ⚖ 504 KB

Condensation of argon/HF mixtures at 12 I( revealed sharp new 38X.5 and 3702.0 cm-' absorptions which exhibited different growth behaviour on sample warming. hlixed HF/DF samples revealed a single mixed isotopic satellite near the DF counterpart of the former band assigned to (HF)z and a group of sa

Ultraviolet absorption spectra of Zn2 an

Ultraviolet absorption spectra of Zn2 and Cd2 in solid argon and krypton at 10 K

✍ Bruce S. Ault; Lester Andrews 📂 Article 📅 1977 🏛 Elsevier Science 🌐 English ⚖ 458 KB

Fluorescence and recombination-emission

Fluorescence and recombination-emission spectra from S2 formed by ultraviolet laser photolysis of CS2 in an argon matrix at 15 k

✍ Hiro-o Hamaguchi; Mitsuo Tasumi 📂 Article 📅 1982 🏛 Elsevier Science 🌐 English ⚖ 243 KB

Two SCII~S of cmwon bands wcrc obscrvcd for the CSz/Ar (I 100-500) system a1 15 K with cultatlon at 257 3 nm They are asslgncd IO B %j -?( 3X-g and U" 311u -. X jri of S2z which was formed by photodlssoclatlon of CS2, CS2 + lw -+ CS + S, followed by recombmauon of two S atoms The 8" 3~,, state b3s b